云顶国际yd222

云顶国际yd222
师资力量

祝良芳     教授

研究方向:生物质能源化学;多相催化

联系方式:18200500400          Email:zhulf@scu.edu.cn

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简历

简介祝良芳,女,19795月生。2007年获四川大学理学博士,现任四川大学教授、博士生导师。主要从事绿色化学的教学和研究工作,主讲《绿色化学》(化本)、《专业英语》(化本)、《绿色化学引论》(化本)和《糖化学》(硕士生课)。

 

学习及工作经历

1998.92002.7:云顶国际yd222,攻读学士(环境化学)

2002.92007.6:云顶国际yd222,攻读硕、博士(物理化学)

2007.72013.6:云顶国际yd222,讲师(绿色化学)

2010.12012.1:新加坡南洋理工大学化学与生物化学系,博士后

2013.72019.8:云顶国际yd222,副教授(物理化学/绿色化学),硕士生导师

2019.9-至今:云顶国际yd222,教授(物理化学/绿色化学),博士生导师

主要研究方向

生物质能源化学;多相催化

主要工作业绩

针对生物质糖高值化利用过程中原料转化反应网络复杂的问题,开展了用于糖转化的新催化剂和过程调控研究,揭示了复杂反应网络的本质及调控规律,阐明了新催化剂的制备科学和催化作用规律。为以可再生的碳水化合物资源为原料合成有用化学品提供了理论基础。

已主持完成国家自然科学青年基金、教育部博士点新教师基金、四川省应用基础研究计划、成都市科技计划、四川大学优秀青年学者科研基金等多项项目,目前承担国家自然科学基金面上项目1项,参研国家重点研发计划课题、973课题、国家自然科学基金重点项目等多项。

代表性成果

(获奖成果、专著、论文、专利)

主要获奖成果                                                                                                                         

1、四川省科技进步三等奖(2008)

2、四川省高等教育教学成果一等奖(2009)

3、四川大学青年骨干教师奖(2009/2015)

4、四川大学本科优秀毕业论文三等奖指导教师(3人次)(2014/2019)

5、四川大学精品开放课程建设突出贡献奖(2014)

6、四川大学课堂教学质量优秀奖(2014/2015/2018/2019)

7、本科教学先进个人奖(全英语授课教学质量优秀奖)(2016/2017)

8、云顶国际yd2222019-2020年度“优秀共产党员”(2020)

9、四川大学2019年课程思政榜样课程(2020)

 

 

代表性论文:

49. Liangfang Zhu, Xing Fu, Yexin Hu, Changwei Hu*. Controlling the Reaction Networks for Efficient Conversion of Glucose to 5-Hydroxymethylfurfural. ChemSusChem, 2020, 13, 4812-4832. (Invited review)

   文本框: The precise control of the reaction pathway toward one particular product (e.g., 5-hydroxymethylfurfural, HMF) is of great importance for effective utilization of biomass-derived carbons. Herein, recent advances on understanding the complicated reaction network involved in glucose-to-HMF transformation and strategies proposed for regulating the reaction pathway toward HMF are presented.

48. Zhongbao Liu, Liangfang Zhu*, and Changwei Hu*. High-Efficiency Synthesis of 5-Hydroxymethylfurfural from Fructose over Highly Sulfonated Organocatalyst. Ind. Eng. Chem. Res., 2020, 59 (39), 17218-17227.

47. Xing Fu, Yexin Hu, Yanru Zhang, Yucheng Zhang, Dianyong Tang, Liangfang Zhu*, Changwei Hu*. Solvent Effects on Degradative Condensation Side Reactions of Fructose in Its Initial Conversion to 5-Hydroxymethylfurfural. ChemSusChem 2020, 13, 501-512. (Front cover)

                                                                           

46. Hong Xie, Ting Qi, Ya-Jing Lyu, Jin-Feng Zhang, Zhen-Bing Si, Li-Juan Liu, Liangfang Zhu, Hua-Qing Yang*. Chang-Wei Hu, Molecular mechanism comparison of decarbonylation with deoxygenation and hydrogenation of 5-hydroxymethylfurfural catalyzed by palladium acetate. Phy. Chem. Chem. Phys. 2019, 21 (7), 3795-3804.


45. Ting Qi, Meng-Fu He, Liangfang Zhu, Ya-Jing Lyu, Hua-Qing Yang*, Chang-Wei Hu*. Cooperative Catalytic Performance of Lewis and Bronsted Acids from AlCl3 Salt in Aqueous Solution toward Glucose-to-Fructose Isomerization. J. Phy. Chem. C 2019, 123 (8), 4879-4891.


44. Jinhang Dai, Zhongbao Liu, Yexin Hu, Shuqing Liu, Linfeng Chen, Ting Qi, Huaqing Yang, Liangfang Zhu*, Changwei Hu*. Adjusting the acidity of sulfonated organocatalyst for the one-pot production of 5-ethoxymethylfurfural from fructose. Catal. Sci. Technol. 2019, 9 (2), 483-492.

43. Shuqing Liu, Xing Fu, Jinhang Dai, Zhongbao Liu, Liangfang Zhu*, Changwei Hu*. One-Pot Synthesis of 2,5-Diformylfuran from Fructose by Bifunctional Polyaniline-Supported Heteropolyacid Hybrid Catalysts. Catalysts 2019, 9 (5).

42. Jinqiang Tang, Liangfang Zhu*, Xing Fu, Jinhang Dai, Xiawei Guo, Changwei Hu*. Insights into the Kinetics and Reaction Network of Aluminum Chloride-Catalyzed Conversion of Glucose in NaCl-H2O/THF Biphasic System. ACS Catal. 2017, 7, 256-266. (Highly Cited in Field)

41. Xing Fu, Jinhang Dai, Xiawei Guo, Jinqiang Tang, Liangfang Zhu*, Changwei Hu*. Suppression of oligomer formation in glucose dehydration by CO2 and tetrahydrofuran. Green Chem. 2017, 19, 3334-3343.

40. Jinhang Dai, Liangfang Zhu*, Dianyong Tang, Xing Fu, Jinqiang Tang, Xiawei Guo, Changwei Hu*. Sulfonated polyaniline as a solid organocatalyst for dehydration of fructose into 5-hydroxymethylfurfural. Green Chem. 2017, 19, 1932-1939. (Highlighted by Synfacts 2017, 13(07), 0769)

39. Xiawei Guo, Jinqiang Tang, Bo Xiang, Liangfang Zhu*, Huaqing Yang, Changwei Hu*. Catalytic Dehydration of Fructose into 5-Hydroxymethylfurfural by a DMSO-like Polymeric Solid Organocatalyst. ChemCatChem 2017, 9, 3218-3225.

38. Like Ren, Liangfang Zhu, Ting Qi, Jinqiang Tang, Huaqing Yang*, Chang Wei Hu*. Performance of Dimethylsulfoxide and Brønsted Acid Catalysts in Fructose Conversion to 5-Hydroxymethylfurfural. ACS Catal. 2017, 7, 2199-2212.


37. Liangfang Zhu, Jinhang Dai, Mingyang Liu, Dianyong Tang, Shuqing Liu, Changwei Hu*. Formyl-Modified Polyaniline for the Catalytic Dehydration of Fructose to 5-Hydroxymethylfurfural. ChemSusChem 2016, 9 (16), 2174-2181.

36. Jinhang Dai, Xing Fu, Liangfang Zhu*, Jinqiang Tang, Xiawei Guo, Changwei Hu*, One-pot Deoxygenation of Fructose to Furfuryl Alcohol via Sequential Dehydration and Decarbonylation. ChemCatChem 2016, 8 (7), 1379-1385.

 

35. Jinqiang Tang, Xiawei Guo, Liangfang Zhu*, Changwei Hu*, Mechanistic Study of Glucose-to-Fructose Isomerization in Water Catalyzed by [Al(OH)2(aq)]+. ACS Catal. 2015, 5, 5097-5103.

34. Yu Liu, Liangfang Zhu*, Jinqiang Tang, Mingyang Liu, Ruodi Cheng, Changwei Hu*. One-pot, One-step Synthesis of 2,5-Diformylfuran from Carbohydrates over Mo-Containing Keggin Heteropolyacids. ChemSusChem 2014, 7 (12), 3541-3547.

33. Wen-wu Liu*, Xiu-ping Wang, Chang-wei Hu, Dong-mei Tong, Liang-fang Zhu, Gui-ying Li. Catalytic pyrolysis of distillers dried grain with solubles: An attempt towards obtaining value-added products. Int. J. Hydrogen Energ. 2014, 39 (12), 6371-6383.


32. Wenwu Liu, Changwei Hu*, Dongmei Tong, Yu Yang, Guiying Li, Liangfang Zhu, Jinqiang Tang. Catalytic effect of KF-846 on the reforming of the primary intermediates from the co-pyrolysis of pubescens and LDPE. Energ Convers Manage 2014, 88, 565-572.


31. Yan Zeng, Bohan Zhao, Liangfang Zhu, Dongmei Tong, Changwei Hu*. Catalytic pyrolysis of natural algae from water blooms over nickel phosphide for high quality bio-oil production. RSC Adv. 2013, 3 (27), 10806-10816.


30. Wenwu Liu, Changwei Hu*, Yu Yang, Dongmei Tong, Liangfang Zhu, Ruinan Zhang, Bohan Zhao. Study on the effect of metal types in (Me)-Al-MCM-41 on the mesoporous structure and catalytic behavior during the vapor-catalyzed co-pyrolysis of pubescens and LDPE. Appl. Catal. B. Environ. 2013, 129, 202-213.


29. Liangfang Zhu, Hong Wang, Xiaoshuang Shen, Liyong Chen, Yawen Wang, Hongyu Chen. Developing Mutually Encapsulating Materials for Versatile Syntheses of Multilayer Metal-Silica-Polymer Hybrid Nanostructures. Small 2012, 8 (12), 1857-1862.

28. Liangfang Zhu, Xiaoshuang Shen, Zhiyuan Zeng, Hong Wang, Hua Zhang, Hongyu Chen. Induced Coiling Action: Exploring the Intrinsic Defects in Five-Fold Twinned Silver Nanowires. ACS Nano 2012, 6 (7), 6033-6039.

27. Xueqin Wang, Xiuli Cao, Xiaoke Hu, Guiying Li, Liangfang Zhu, Changwei Hu*. Effect of zirconium addition on vanadium-catalyzed toluene oxidation by H2O2 in CH3COOH. J. Mol. Catal. A: Chem. 2012, 357, 1-10.


26. Hong Wang, Liyong Chen, Xiaoshuang Shen, Liangfang Zhu, Jiating He, Hongyu Chen*. Unconventional Chain-Growth Mode in the Assembly of Colloidal Gold Nanoparticles. Angew. Chem. Int. Ed. 2012, 51 (32), 8021-8025.


25. Dianyong Tang*, Liangfang Zhu, Changwei Hu*. Elucidating active species and mechanism of the direct oxidation of benzene to phenol with hydrogen peroxide catalyzed by vanadium-based catalysts using DFT calculations. RSC Adv. 2012, 2 (6), 2329-2333.


24. Yuhua Feng, Jiating He, Hong Wang, Yee Yan Tay, Hang Sun, Liangfang Zhu, Hongyu Chen*. An Unconventional Role of Ligand in Continuously Tuning of Metal-Metal Interfacial Strain. J. Am. Chem. Soc. 2012, 134 (4), 2004-2007.


23. Hang Sun, Jia Ting He, Shuangxi Xing, Liangfang Zhu, Yi Jian Wong, Yawen Wang, Hongju Zhai, Hongyu Chen*. One-step synthesis of composite vesicles: Direct polymerization and in situ over-oxidation of thiophene. Chem. Sci. 2011, 2 (11), 2109-2114.


22. Xiaoshuang Shen, Liyong Chen, Dehui Li, Liangfang Zhu, Hong Wang, Cuicui Liu, Yong Wang, Qihua Xiong, Hongyu Chen*. Assembly of Colloidal Nanoparticles Directed by the Microstructures of Polycrystalline Ice. ACS Nano 2011, 5 (10), 8426-8433.


21. Yi Jian Wong, Liangfang Zhu, Wei Shan Teo, Yan Wen Tan, Yanhui Yang, Chuan Wang*, Hongyu Chen*. Revisiting the Stober Method: In homogeneity in Silica Shells. J. Am. Chem. Soc. 2011, 133 (30), 11422-11425.

 

20. Xiaoke Hu, Liangfang Zhu, Bin Guo, Qiuyuan Liu, Guiying Li, Changwei Hu*. Hydroxylation of Benzene to Phenol via Hydrogen Peroxide in Hydrophilic Triethylammonium Acetate Ionic Liquid. Chem Res. Chinese U. 2011, 27 (3), 503-507.


19. Xiao Ke Hu, Liang Fang Zhu, Xue Qin Wang, Bin Guo, Jia Quan Xu, Gui Ying Li, Chang Wei Hu*, Active species formed in a Fenton-like system in the medium of triethylammonium acetate ionic liquid for hydroxylation of benzene to phenol. J. Mol. Catal. A: Chem. 2011, 342-43, 41-49.


18. Bin Guo, Liangfang Zhu, Xiaoke Hu, Qian Zhang, Dongmei Tong, Guiying Li, Changwei Hu*, Nature of vanadium species on vanadium silicalite-1 zeolite and their stability in hydroxylation reaction of benzene to phenol. Catal. Sci. Technol. 2011, 1 (6), 1060-1067.


17. Liyong Chen, Hong Wang, Jun Xu, Xiaoshuang Shen, Lin Yao, Liangfang Zhu, Zhiyuan Zeng, Hua Zhang, Hongyu Chen*. Controlling Reversible Elastic Deformation of Carbon Nanotube Rings. J. Am. Chem. Soc. 2011, 133 (25), 9654-9657.


16. Jia Xi Zhang, Jia Luo, Dongmei Tong, Liangfang Zhu, Linlin Dong, Changwei Hu*. The dependence of pyrolysis behavior on the crystal state of cellulose. Carbohyd. Polym. 2010, 79 (1), 164-169.


15. Pan Pan, Changwei Hu*, Wenyan Yang, Yuesong Li, Linlin Dong, Liangfang Zhu, Dongmei Tong, Renwei Qing, Yong Fan. The direct pyrolysis and catalytic pyrolysis of Nannochloropsis sp residue for renewable bio-oils. Bioresource Technol 2010, 101 (12), 4593-4599.


14. Jia Luo, Yong Xu, Lingjie Zhao, Linlin Dong, Dongmei Tong, Liangfang Zhu, Changwei Hu*. Two-step hydrothermal conversion of Pubescens to obtain furans and phenol compounds separately. Bioresource Technol 2010, 101 (22), 8873-8880.


13. Wenwu Liu, Changwei Hu*, Yu Yang, Liangfang Zhu, Dongmei Tong. Effect of the Interference Instant of Zeolite HY Catalyst on the Pyrolysis of Pubescens. Chinese J Chem Eng 2010, 18 (2), 351-354.


12. Wen Wu Liu, Chang Wei Hu*, Yu Yang, Dong Mei Tong, Gui Ying Li, Liang Fang Zhu. Influence of ZSM-5 zeolite on the pyrolytic intermediates from the co-pyrolysis of pubescens and LDPE. Energ. Convers. Manage. 2010, 51 (5), 1025-1032.


11. Dianyong Tang, Liangfang Zhu, Changwei Hu*. Comprehensive DFT Study of the Mechanism of Vanadium-Catalyzed Amination of Benzene with Hydroxylamine. Organometallics 2011, 30 (21), 5675-5686.


10. Qiuyuan Liu, Liangfang Zhu, Li Li, Bin Guo, Xiaoke Hu, Changwei Hu*. Selective activation of C-H bonds on the ring of ethylbenzene catalyzed by several diperoxovanadate complexes. J. Mol. Catal. A: Chem. 2010, 331 (1-2), 71-77.

9. Yufen Lue, Liangfang Zhu, Qiuyuan Liu, Bin Guo, Xiaoke Hu, Changwei Hu*. Direct amination of benzene to aniline with several typical vanadium complexes. Chinese Chem. Lett. 2009, 20 (2), 238-240.


8. Yongke Zhong, Guiying Li, Liangfang Zhu, Dianyong Tang, Changwei Hu*. Direct catalytic hydroxylation of several typical aromatic compounds over Fe/activated carbon catalyst. Chem. J. Chinese U. 2007, 28 (8), 1570-1572.


7. Yong Ke Zhong, Gui Ying Li, Liang Fang Zhu, Yun Yan, Gang Wu, Chang Wei Hu*. Low temperature hydroxylation of benzene to phenol by hydrogen peroxide over Fe/activated carbon catalyst. J. Mol. Catal. A: Chem. 2007, 272 (1-2), 169-173.


6. Junping Wu, Xueqin Wang, Liangfang Zhu, Guiying Li, Changwei Hu*. Selective Oxidation of Toluene with Hydrogen Peroxide Catalyzed by V-Mo-based Catalyst. Chem. Res. Chinese U. 2007, 23 (5), 585-591.


5. Liangfang Zhu, Bin Guo, Dianyong Tang, Xiaoke Hu, Guiying Li, Changwei Hu*. Sodium metavanadate catalyzed one-step amination of benzene to aniline with hydroxylamine. J. Catal. 2007, 245 (2), 446-455.

 

4. Changwei Hu*, Liangfang Zhu, Yunsheng Xia. Direct amination of benzene to aniline by aqueous ammonia and hydrogen peroxide over V-Ni/Al2O3 catalyst with catalytic distillation. Ind Eng Chem Res 2007, 46 (10), 3443-3445.


3. Min Jian, Liangfang Zhu, Jinyue Wang, Jin Zhang, Guiying Li, Changwei Hu*. Sodium metavanadate catalyzed direct hydroxylation of benzene to phenol with hydrogen peroxide in acetonitrile medium. J. Mol. Catal. A: Chem. 2006, 253 (1-2), 1-7.


2. Yunsheng Xia, Liangfang Zhu, Guiying Li, Changwei Hu*. Direct oxido-amination of benzene to aniline over nickel-vanadium catalysts. Acta Phys-Chim Sin 2005, 21 (12), 1337-1342


1. Tong Chen, Zhenjin Fu, Liangfang Zhu, Changwei Hu*, Anmin Tian, Direct synthesis of aniline by oxido-amination of benzene with H2O2 and aqueous ammonia on Ni-Zr-Ce/Al2O3 catalyst. Acta Chimica Sinica 2003, 61 (11), 1701-1703.

 

专著:

 

1. 胡常伟,李建梅,祝良芳,童冬梅,李丹. 《生物质转化利用》(绿色化学前沿丛书,韩布兴总主编),科学出版社,201911月(第4章:糖类化合物的转化,11.0万字)

 

2. Liangfang Zhu   and Changwei Hu,* Ionic Liquids: “Green” Solvent for Catalytic Oxidations   with Hydrogen Peroxide, in "Ionic Liquids - New Aspects for the   Future" (Eds. Jun-ichi Kadokawa, ISBN 978-953-51-0937-2), Intech   Publisher, Croatia, 2013.1.23, Chapter 14, P349-364.

封面 

 

3. Liangfang Zhu   and Changwei Hu,* Aniline Production: From Multiple Steps to One Step, in   “Aniline: Structural/Physical Properties, Reactions and Environmental   Effects” (Eds. Kenneth Hernandez, and Maria Holloway, ISBN:   978-1-62417417-9), Nova Science Publisher Inc, New York, 2013.4.15, Chapter   3, P91-120.

封面 

 

部分申请及授权专利:

1. 胡常伟,祝良芳,夏云生

由苯直接氧化胺化一步合成苯胺的催化剂制备方法,

中国发明专利,专利号:ZL2004100216360,授权日:2006118日。

2. 胡常伟,祝良芳,夏云生,李桂英

一种由苯直接氧化胺化一步合成苯胺的方法,

中国发明专利,专利号:ZL2005100205055,授权日:200924日。

3. 祝良芳,刘玉,胡常伟,唐金强,常欢

一种由碳水化合物一步催化合成2,5-呋喃二甲醛的方法,

中国发明专利,专利号:ZL201310027325.4,授权日:201563日。

4. 祝良芳,刘玉,胡常伟,唐金强

一种从DMSO溶液中分离2,5-呋喃二甲醛的方法,

中国发明专利,专利号:ZL201410088001.6,授权日:201578日。

5. 祝良芳,付兴,代金杭,胡常伟

一种由二氧化碳促进的碳水化合物合成5-羟甲基糠醛的方法,

中国发明专利,专利号:ZL201510099261.8,授权日:2016112日。

6. 祝良芳,代金杭,付兴,胡常伟

一种用于合成5-羟甲基糠醛的改性聚苯胺催化剂的制备方法,

中国发明专利,专利号:ZL201610033921.7,授权日:20171110日。

7. 祝良芳,代金杭,胡常伟

一种用磺化聚苯胺催化碳水化合物合成5-羟甲基糠醛的方法,

中国发明专利,专利号:201610599561.7,授权日:2018921日。

 

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